| | 1 | Baltasar Albéniz | Oct 25, 1942 | | 3:1 | | - |
| | 3 | Ricardo Comesaña | Dec 24, 1939 | | 2:3 | | - |
| | 4 | Ricardo Comesaña | Dec 17, 1939 | | 6:1 | | - |
| | 3 | Ricardo Comesaña | Dec 3, 1939 | | 3:2 | | - |
| | 103 | Ricardo Comesaña | Dec 31, 1939 | | 1:4 | | 15 years 08 months 11 days |
| | 68 | Víctor Fernández | Mar 12, 2000 | | 3:0 | | 16 years 08 months 25 days |
| | 268 | Paco Herrera | Feb 16, 2013 | | 3:1 | | 17 years 02 months 09 days |
| | 18 | Eduardo Coudet | May 16, 2021 | | 1:2 | | 17 years 04 months 27 days |
| | 24 | Óscar García | Oct 4, 2020 | | 2:0 | | 17 years 05 months 05 days |
| | 17 | Ricardo Comesaña | Dec 31, 1939 | | 1:4 | | 17 years 05 months 27 days |
| | 121 | Abel Resino | May 26, 2013 | | 0:2 | | 17 years 10 months 01 day |
| | 1 | Milorad Pavić | Mar 26, 1983 | | 4:0 | | 17 years 10 months 23 days |
| | 2 | Fran Escribá | Aug 17, 2019 | | 1:3 | | 18 years 16 days |
| | 1 | Eduardo Berizzo | Dec 5, 2015 | | 1:1 | | 18 years 03 months 10 days |
| | 9 | Eduardo Coudet | Oct 25, 2021 | | 0:3 | | 18 years 03 months 23 days |
| | 50 | Óscar García | Sep 19, 2020 | | 2:1 | | 18 years 03 months 23 days |
|
| 40 | Eduardo Berizzo | Dec 12, 2015 | | 1:0 | | 18 years 04 months 04 days |
| | 40 | Luis Enrique | Aug 25, 2013 | | 1:2 | | 18 years 04 months 30 days |
| | 183 | Paco Herrera | Sep 1, 2012 | | 2:0 | | 18 years 05 months 29 days |
| | 17 | Baltasar Albéniz | Nov 28, 1943 | | 1:2 | | 18 years 06 months 15 days |
| | 266 | José María Maguregui | Aug 29, 1987 | | 0:1 | | 18 years 07 months 01 day |
| | 16 | Carlos Carvalhal | Nov 5, 2022 | | 1:2 | | 18 years 09 months 04 days |
| | 65 | Odilo Bravo | Jan 11, 1953 | | 5:1 | | 18 years 11 months 23 days |
| | 40 | Juan Arza | Oct 3, 1971 | | 4:0 | | 18 years 11 months 29 days |
| | 10 | Eduardo Berizzo | Aug 24, 2014 | | 3:1 | | 19 years 08 days |