| | 33 | José Villar Fernández | Apr 16, 1988 | | 0:0 | | 22 years 08 months 20 days |
| | 30 | Ricardo Zamora | Dec 21, 1947 | | 7:1 | | 22 years 08 months 22 days |
| | 86 | Juan Carlos Unzué | Aug 19, 2017 | | 2:3 | | 22 years 08 months 25 days |
| | 6 | Antonio Mohamed | Oct 1, 2018 | | 1:1 | | 22 years 08 months 30 days |
| | 1 | Lluís Miró | Mar 8, 1959 | | 0:1 | | 22 years 09 months 11 days |
| | 7 | Fran Escribá | Sep 15, 2019 | | 0:2 | | 22 years 09 months 29 days |
| | 29 | Fernando Vázquez | Sep 17, 2006 | | 2:1 | | 22 years 10 months 08 days |
| | 3 | Milorad Pavić | Feb 9, 1983 | | 1:0 | | 22 years 10 months 10 days |
| | 7 | Ricardo Zamora | Oct 27, 1946 | | 3:2 | | 22 years 10 months 13 days |
| | 142 | Ricardo Zamora | Sep 22, 1946 | | 1:1 | | 22 years 10 months 13 days |
| | 17 | Ricardo Zamora | Sep 26, 1954 | | 2:2 | | 22 years 10 months 28 days |
| | 2 | Luis Pasarín | Sep 14, 1958 | | 0:3 | | 22 years 11 months 27 days |
| | 43 | Joaquín Cárdenes | Oct 6, 1940 | | 7:1 | | 23 years 06 days |
| | 28 | Carlos Aimar | Nov 27, 1994 | | 0:0 | | 23 years 18 days |
| | 1 | Carlos Carvalhal | Apr 22, 2023 | | 2:0 | | 23 years 27 days |
| | 13 | Milorad Pavić | Oct 17, 1982 | | 2:0 | | 23 years 01 month 04 days |
| | 1 | Eduardo Berizzo | Aug 23, 2015 | | 1:2 | | 23 years 01 month 28 days |
| | 83 | Ricardo Zamora | Oct 24, 1948 | | 2:2 | | 23 years 02 months 29 days |
| | 2 | Óscar García | Jun 27, 2020 | | 2:2 | | 23 years 03 months 02 days |
|
| 150 | José Novoa | Sep 17, 1989 | | 2:0 | | 23 years 03 months 07 days |
|
| 50 | Víctor Fernández | Aug 26, 2001 | | 0:3 | | 23 years 03 months 11 days |
| | 53 | Félix Carnero | Aug 31, 1985 | | 1:1 | | 23 years 03 months 27 days |
| | 1 | Luis Pasarín | Nov 9, 1958 | | 2:0 | | 23 years 03 months 30 days |
| | 3 | Juan Arza | Mar 15, 1970 | | 1:2 | | 23 years 04 months 05 days |
| | 44 | Ricardo Zamora | Oct 24, 1948 | | 2:2 | | 23 years 04 months 06 days |